Chemical modeling of gold mineralisation in the Lachlan Fold Belt shows that gold can be precipitated over a wide temperature range (from 320 to 200 ?C in this study) from CO2-bearing, low salinity, aqueous fluid flowing upwards through faults in turbiditic sequences. In agreement with field observations, the veins are predicted to be mostly quartz (> 93 vol.%) with minor amounts of pyrite, arsenopyrite and muscovite (sericite) precipitating above 230 ?C. The predicted alteration assemblage contains pyrite, arsenopyrite, calcite, muscovite (sericite), chlorite and feldspar. Varying some of the chemical characteristics of the initial fluid has resulted in the following changes to the model: Preventing the fluid from boiling stops gold precipitating below 310 ?C but has little effect on the vein mineralogy or the mineralogy of the surrounding alteration assemblage. Removing CO2 from the fluid also prevents gold precipitation in the veins below 300 ?C. The modeling also generates an alteration assemblage with a number of Ca-rich minerals as less calcium carbonate exists in this system. Removing sulfur species from the initial fluid decreases the amount of gold precipitated by more than a factor of ten, which is to be expected if sulfur ligands are the main species for gold transport. However, the vein assemblage and the lack of sulfide minerals in the surrounding alteration assemblage also suggest that sulfur species are important in this mineral system. Increasing the initial oxidation state (?O2) of the fluid inhibits gold precipitation in the veins above 260 ?C and leads to a high proportion of dolomite in the surrounding alteration assemblage. On the other hand, decreasing the initial oxidation state of the fluid lead to gold precipitation over a range of temperatures below 310 ?C but predicts that mainly graphite ? quartz precipitates in the veins and that the surrounding alteration assemblage is dominated by feldspar proximal to the veins. This style of mineralogy is not commonly observed in gold deposits in the Lachlan Fold Belt. Increasing the initial pH of the fluid inhibits the amount of minerals that precipitate in the veins, which are dominated by calcite at high temperatures and graphite at low temperatures and corresponding minor amounts of gold. The proximal alteration assemblage is dominated by K-feldspar with amphibole, biotite and epidote. This mineral assemblage is not commonly observed in these deposits. Decreasing the initial pH of the fluid allows gold to precipitate below 280 ?C but generates a proximal alteration assemblage dominated by pyrophyllite, which again is not commonly observed. The results are in agreement with the widely accepted premise that gold is transported as bisulfide complexes and that the ore-bearing fluid is typically a low-salinity, mixed aqueous-carbonic fluid with low-moderate CO2 contents (Ridley and Diamond, 2000). However, the modeling has shown that the absence of certain physico-chemical processes or fluid constituents, such as boiling or lack of CO2 may inhibit gold precipitation in some environments. Large fluctuations in ?O2 or pH will also significantly change the vein and alteration mineralogy and generally reduce the amount of gold that is precipitated. This suggests that these fluids remain rock buffered during their journey from the source to the trap site.

At the Sandpiper gold deposit in the Tanami region of northern Australia sericite is intimately intergrown with arsenopyrite in gold-bearing quartz veins and breccias, suggesting sericite crystallisation synchronous with gold-bearing fluid flow. This ore-stage sericite yields a 40Ar/39Ar plateau age of 1785 ± 16 Ma (1?? including all known systematic uncertainties). Recalculation using revised and more precise values for the 40K decay constants and the age of the Fish Canyon Sanidine standard shifts the age to 1792 ± 6 Ma (1???including all known systematic uncertainties). Given the possibility of post-mineralization isotopic resetting this age can be conservatively interpreted as a minimum constraint on the timing of gold deposition although, given local geological relationships and estimates for the argon retentivity of white mica, we consider complete isotopic resetting to be unlikely. The preferred interpretation is, therefore, that the sericite 40Ar/39Ar age indicates the timing of gold mineralization. The sericite age accords with a limited dataset of 207Pb/206Pb xenotime ages of ~1800 Ma from other gold deposits in the Tanami region, interpreted as mineralization ages. The agreement between independently-derived ages from several gold deposits lends support for a widespread gold-mineralizing event at ~1800 Ma in the Tanami region.

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The North Pilbara Terrane has the largest variety of mineral deposits of any Archaean province. It contains the oldest known examples of volcanic-hosted massive sulphide (VHMS), lode Au, porphyry Cu, orthomagmatic Ni-Cu-PGE-V, pegmatitic Ta-Sn and epithermal deposits, with a diversity more characteristic of Phanerozoic mobile belts. Despite this diversity the North Pilbara Terrane appears to lack any major mineral deposits, with the exception of the Wodgina Ta-Sn pegmatite field. Below, we present the metallogenic history of the North Pilbara Terrane in the context of its tectonic development and then compare it to other Archaean provinces to assess controls on metal endowment.

This solid geology map combines information from aeromagnetic and gravity interpretation by the author at 1:100 000 scale with that from outcrop geology to provide a continuous representation of the distribution of Palaeoproterozoic and Archaean rocks. The Mapping of outcrop geology for Leonora 1:250 000 map Sheet (2nd Edition) was undertaken by Duggan MB, Williams PR, Jagodzinski EA, Rattenbury M, Champion DC, Stewart AJ and Bastrakova IV, largely as part of the National Geoscience Mapping Accord (NGMA -1990 to 2000). Briefly, the data set and map present geological boundaries/units, faults, fractures, folds, veins, dykes, joints, marker beds, trends, structural measurements, and mineral deposits.

Mapping of outcrop geology on Leonora SH51-1 1:250 000 map in the Eastern Goldfields, Western Australia.

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